SUB-DOPPLER SPECTROSCOPY USING A MULTIPLE REFLECTION MIRROR SYSTEM

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1985

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Ohio State University

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When a Fresnel rhomb is used for sub-Doppler Lamb dip spectroscopy, the returning beam is precisely collimated with the ongoing beam. Therefore we can use a multiple reflection mirror system to increase the path length and thus the sensitivity. Such a technique has been incorporated into our CO2 laser microwave modulation sideband system. The increased sensitivity has made it possible to resolve some of the hyperfine structure of the band of NH3 which was previously not resolved. The application of the method to other molecules, such as $SiF_{4}, $SE and PH2, will also be presented.

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Author Institution: Department of Chemistry and Department of Astronomy and Astrophysics, University of Chicago

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