PULSED DISCHARGE JET SPECTROSCOPY OF THE $\tilde{A}A' - \tilde{X}^{1}A'$ BAND SYSTEMS OF SILYLENES AND GERMYLENES
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Abstract
Jet-cooled laser induced fluorescence spectra of HSiCl, DSiCl, HSiBr, DSiBr, HGeCl, and DGeCl have been obtained by diluting appropriate trihalosilane or germane precursors with argon and expanding them through a pulsed electric discharge. The upper state harmonic frequencies, anharmonicities, and isotope shifts were obtained from detailed vibrational analyses of the spectra. In favorable cases, the
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Author Institution: Department of Chemistry, University of Kentucky