HIGH RESOLUTION INFRARED SPECTRUM OF THE $2\nu_{1}$ BAND OF $NO_{2}$

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1974

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Ohio State University

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Abstract

The B-type band, 2ν1, of NO2 at 2627.376cm−1 has been studied with resolution of 0.030cm−1. This weak band exhibits striking intensity perturbations similar to those observed in the 2ν3 band previously reported. The P aide of 2ν1 is very such weaker than the R side of the band; moreover, on the P side of the band, only PRK and PQK line series are observed. The PPK series are conspicuously missing. The stronger R side of the band consists only of very strong RRK series and weaker PPK series. RQK branch lines are observed for K>3. Upper state rotational and spin splitting constants will be reported.

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Author Institution: National Bureau of Standards

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