PFI-ZEKE SPECTROSCOPY OF Be$_{2}$O
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Date
2010
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Publisher
Ohio State University
Abstract
The PFI-ZEKE spectrum of Be$_{2}$O$^{+}$ ion was recorded to obtain accurate ionization energy for Be$_{2}$O and vibrational frequency data for Be$_{2}$O$^{+}$. A short progression of the bending mode was observed, which included bands involving odd changes in the vibrational quanta. This observation indicates that the ion and/or the intermediate state used in the excitation process deviate from D$_{\infty{}}h}$ symmetry.
Description
Author Institution: Department of Chemistry, Emory University, Atlanta, GA; 30322