THERMOCHEMICAL INFORMATION AND ROTATIONAL STRUCTURE IN THE AUTOIONIZATION SPECTRA OF HCO.

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1998

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Ohio State University

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Rotationally resolved autoionization spectra of the HCO radical in high-Rydberg states built on the (010) core vibrational state have been obtained from selected rovibrational levels of the 3pπ2Π(010)Σ+ Rydberg state. Simulations of the spectra lead to reliable ionization potentials for detailed rovibrational states of HCO+. Data for bending overtones supply information on anharmonic terms in the cation vibrational potential. Rotational structure associated with autoionizing states is analyzed.

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Author Institution: Department of Chemistry, Purdue University; Department of Chemistry, National Tsing Hua University

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http://hdl.handle.net/1811/19151

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999