THE $\tilde{A}^{2}\Pi_{u} -\tilde{X}^{2}\Pi_{g}$ TRANSITION OF ${CS_{2}}^{+}$ IN SOLID Ne: NEW ASSIGNMENT OF SOME VIBRONIC LINES

Loading...
Thumbnail Image

Date

1995

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

The A~2ΠuX~2Πg system of CS2+ isolated in solid Ne was investigated by laser-induced fluorescence. Dispersed fluorescence spectrum in the range 475-570 nm and fluorescence excitation spectrum in the range 410-480 nm showed distinct vibrational progressions. Previous studies1,2 reported irregular vibrational spacings for the A~ and X~ states due to Fermi resonance. We have carefully determined the line positions of the A~X~ system of 12C32S2+,13C32S2+, and 12C34S2+. By comparison of 13C-isotopic shifts relative to 34S-isotopic shifts for the corresponding lines, we were able to assign each component of the Fermi polyad. Our new assignments for the X~ state are different from previous ones, for example: the (1,2,0) and (2,0,0) are interchanged, and the (1,4,0) and (3,0,0) are also interchanged; these new assignments agree with recent theoretical calculations3. Similarly, we also propose new assignments for the vibronic lines of the A~ state.

Description

  1. V. E. Bondybey, J. H. English, and T. A. Miller, J. Chem. Phys. 70, 1621 (1979). 2. V. E. Bondybey and J. H. English, J. Chem. Phys. 73, 3098 (1980). 3. M. Brommer and P. Rosumus, Chem. Phys. Lett. 206, 540 (1993).

Author Institution: National Tsing Hua University, Hsinchu, Taiwan 30043.

Keywords

Citation