HIGH RESOLUTION INFRARED SPECTROSCOPY OF THE $Ar-H_{2}0$ VAN DER WALLS COMPLEX - VIBRATIONAL ENERGY TRANSFER IN WEAKLY BOUND COMPLEXES

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1990

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Ohio State University

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We report the first near-infrared study of the ArH2O van der Waals complex. Three bands, all involving the asymmetric stretch of the $H_{2}O $ submit, are observed. In conjunction with far-infrared data of Cohen etal.1, these allow determination of the intermolecular angular potential for the ground vibrational state of the complex. We find a smaller barrier for in-plane versus out-of-plane internal rotation of the water molecule within the complex. One of the bands exhibits perturbations of frequencies and line widths which reveal a resonance with a predissociative, H2O symmetric scratch excited state. Analysis of the data provides evidence for both intra and intermolecular vibrational energy flow in the complex.

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1 R.C. Cohen, K.L. Busarow, K.B. Laughlin, G.A. Blake. M. Havenith, Y.T. Lee, and R.J. Saykally. J. Chem. Phys. 89. 4494 (1988).


Author Institution: Joint Institute for Laboratory Astrophysics, University of Colorado, and National Institute of Standards and Technology, and the Department of Chemistry and Biochemistry, University of Colorado

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