PHOTOACOUSTIC PRESSURE BROADENING MEASUREMENTS OF TRANSITIONS IN THE $O_{2} b^{1}{\Sigma_{8}}^{+} \leftarrow X^{3}{\Sigma_{8}}^{-}$ $BANDS^{\ast}$

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1982

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Ohio State University

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High-resolution spectra of individual rotational lines in the 0-0 and 1-0 bands of oxygen (762 and 668 nm, respectively) have been measured photoacoustically. Line strengths and pressure broadening coefficients have been determined for both self broadening and foreign-gas broadening at pressures up to 3 atm. Comparison of these measurements with previous observations1,2 permits the calibration of the photoacoustic detector response. The importance of the modulation frequency in the absolute calibration is discussed.

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This research was conducted under the McDonnell Douglas Independent Research and Development program. 1D.E. Burch and D.A. Gryvnak, Appl. Opt. 8, 1493(1969). 2L.P. Giver, R.W. Boese, and J.H. Miller, J. Quant. Spectrose. Radiat. Transfer 14, 793 (1974).

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