MOLECULAR BEAM ELECTRIC RESONANCE SPECTRUM OF LITHIUM HYDRIDE

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1961

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Ohio State University

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The molecular beam electric resonance spectra of lithium hydride and lithium deuteride have been measured. The principal transition studied is J=1, MJ=0→J=1. MJ=±1 in a strong electric field. The derived molecular parameters are presently: [FIGURE] Single lines can be measured with a precision of approximately 100 cycles/second. Therefore the values of the constants are capable of being further refined with our present spectral data. A discussion of the chemical significance of the experimental molecular parameters, together with a comparison with those obtained from \emph{ab initio} calculations, will be presented.

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Author Institution: Chemistry Department, Harvard University

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