MICROWAVE AND MICROWAVE-MICROWAVE DOUBLE RESONANCE SPECTROSCOPY OF TORSIONALLY EXCITED METHYL FORMATE

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1986

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Ohio State University

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Initial measurements of the rotational transition frequencies of methyl formate in its first excited torsional state will be presented. In this work, standard Stark spectroscopy in the 11-28 GHz range has been augmented by the use of microwave-microwave double resonance spectroscopy, which aide in the location and assignement of rotational transitions belonging to the same torsional state. Computational methods will be discuased as well.

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Address of Plummer: I. Physikalisches Institut, Universait\""{a}t zu K\""{o}ln, Z\""{u}lpicher Strasse 77, 5000 K\""{o}ln 41 Fed. Republic of Germany. Address of Walters and Baker: Schuster Laboratory, University of Manchester, Manchester M13 9PL England. G. M. P. acknowledges the support of the Alexander von Humboldt-Stiftunr, Bonn.
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