VIBRATIONAL SPECTRA OF THE $LiClO_{4}$ MONOMER, GLASS, LIQUID AND CRYSTAL

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1972

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Ohio State University

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Volatilization of LiClO4 permits the vapor deposition of the glass phase as well as matrix isolation of monomeric LiClO4. The strong distortion of the tetrahedral ClO4 anion in the 1:1 association with lithium can be viewed as a limiting case and, thus, is informative regarding cation-anion interactions in other media, such as molten salt systems. The monomer and glass spectra will be contrasted with data for the melt and crystal phases.

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Author Institution: Department of Chemistry, Oklahoma State University

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http://hdl.handle.net/1811/8914

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979