INFRARED SPECTRUM OF BIACETYL ADSORBED ON ALKALI HALIDE FILMS

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Date

1999

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Ohio State University

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Abstract

The infrared spectrum of biacetyl ((CH3CO)2) adsorbed onto sublimated films of alkali halides was observed. The infrared active C-H stretching modes are blue-shifted relative to the gas phase values, while the asymmetric carbonyl stretch is red-shifted. Surface-induced splitting has been observed in the asymmetric methyl rocking mode. Temperature-dependent broadening of the asymmetric methyl vibrations was observed. The vibrational shifts and splittings will be used, along with desorption kinetics, to determine the mode of adsorption for this molecule.

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Author Institution: Department of Chemistry, University of Scranton

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