RELAXATION AND SPECTROSCOPY OF $Ca_{2}$ IN RARE GAS MATRICES

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1978

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Ohio State University

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Coherent and incoherent reemission from matrix isolated Ca2 were studied. The ground state vibrational levels of Ca2 exhibit broadening duo to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The Ca2 molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the Lattice.

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Author Institution: Bell Laboratories

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http://hdl.handle.net/1811/10549

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979