RELAXATION AND SPECTROSCOPY OF $Ca_{2}$ IN RARE GAS MATRICES
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Date
1978
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Ohio State University
Abstract
Coherent and incoherent reemission from matrix isolated $Ca_{2}$ were studied. The ground state vibrational levels of $Ca_{2}$ exhibit broadening duo to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The $Ca_{2}$ molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the Lattice.
Description
Author Institution: Bell Laboratories