QUANTITATIVE STUDY OF EXCITATION PROFILES OF TOTALLY SYMMETRIC AND NONTOTALLY SYMMETRIC VIBRATIONS OP PYRAZINE WITH TUNABLE UV LASERS--A CRITICAL EXAMINATION OF VARIOUS THEORIES OF RAMAN INTENSITIES

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1977

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Ohio State University

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The resonant Raman effect of pyrazine was studied quantitatively with tunable UV lasers at liquid helium temperature. Solid solutions of pyrazine in benzene with various concentrations (3% to 0.1%) were used. Using the 990 cm−1 benzene vibration as reference, the excitation profiles of Raman intensities for ν1,ν9,ν6a, and ν10a were determined. It was found that both ν6a and ν10a are enhanced by a factor of 106. The functional dependence is quite different for different vibrations, e.g., ν6a shows a (ΔE)−2 dependence $(\Delta E $ is the difference between the excitation energy and the resonance), whereas, ν10a shows a (ΔE)−4 dependence off resonance and a (ΔE)−1 dependence near resonance. Existing theories by Albrecht, Peticolas, etc., would predict (ΔE)−4 off resonance and (ΔE)−2 near resonance for ν10a and (ΔE)−4 for ν6a throughout.

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Author Institution: Radiation Laboratory University of Notre Dame

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