THE INFRARED SPECTRA OF HCN AND DCN
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Date
1955
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Publisher
Ohio State University
Abstract
The infrared spectra of HCN and DCN have been observed from 1900 to $8000 cm^{-1}$. The rotational structure has been analyzed for most of the bands yielding values for $\nu_{0}$, ${B}^{\prime}-{B}^{\prime\prime}$, and $B_{0}$. The value of $B_{0}$ compares well with previous measurements. Values for all the anharmonic and interaction terms of the vibrational energy expression have been obtained for both of the molecules. The $\omega_{e}$’s obtained from these terms check the isotope rule.
Description
Author Institution: National Bureau of Standards