THE ROTATIONAL SPECTRUM OF AMINOETHANOL $(NH_{2}CH_{2}CH_{2}OH)$

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2002

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Ohio State University

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The rotational spectrum of aminoethanol (NH2CH2CH2OH) has been characterized in the 75−120 GHz region using the 1-meter flow cell apparatus at the Jet Propulsion Laboratory. Previous studies of the rotational spectrum of aminoethanol in the 8−40 GHz region probed the ground state to the J=8 level and included determination of the dipole moment and rotational constants.a Fourth-order centrifugal distortion constants were subsequently determined from these data.b We present here extended measurements of the ground state transitions up to J=51, as well as ν27=1 transitions up to J=50,ν26=1 transitions up to J=35, and ν25=1 transitions up to J=29. Rotational transitions from the ν27=2,ν26=2, and ν25=2 states as well as three combination bands have also been assigned. Spectroscopic parameters, including standard rotational constants and fourth- and sixth-order centrifugal distortion constants, were determined using the SPFit/SPCat program suite.

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a Penn R. E. and Curl R. F. (1971) J. Chem. Phys. 53, 651 - 658. b Kaushik V. K. and Woods R. C. (1982) Z. Phys. Chem. Neue Fol. 132, 117 - 120.


Author Institution: Division of Chemistry, California Institute of Technology; California Institute of Technology, Jet Propulsion Laboratory, Microwave Millimeter and Submillimeter Spectroscopy Lab; Division of Geology and Planetary Science, California Institute of Technology

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