INFRARED SPECTRUM OF DINITROGEN TRIOXIDE

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Date

1971

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Ohio State University

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The infrared spectrum of gaseous $N_{2}O_{3}$ at room temperature is difficult to analyze due to the interfering absorptions of $NO_{2}$ and $N_{2}O_{4}$ which are also present. At reduced temperatures however, the vapor pressure of $NO_{2}$ and $N_{2}O_{4}$ becomes negligible with respect to that of $N_{2}O_{4}$. Utilizing path lengths up to 30 meters and temperatures around -- $120^{\circ} C$ the vibration rotation bands of $N_{2}O_{3}$ are easily recorded and analyzed.

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Author Institution: Department of Chemistry, Indiana University

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