ELECTRONIC SPECTRA OF THIOFORMALDEHYDE, SELENOFORMALDEHYDE, AND OTHER SMALL MOLECULES BY CHEMILUMINESCENCE

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1986

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Ohio State University

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Abstract

Phosphorescence from the a3A2 state of CH2S,CD2S, and CH2 Se has been observed in the reactions of F2 with CH3SH,CD3SH, and CH3Se2CH3. Details of the vibronic spectra of these molecules will be discussed. The spectral features observed in the reaction of F2 with CS2 will also be examined as they relate to CS2 (a) or FCS(A) being the emitter.

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Address of Glinski: National Center for Atmospheric Research, P. O. Box 3000, Boulder, CO 80307. Address of Birks: Department of Chemistry and CIRES, University of Colorado, Boulder 80309.


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