MEASUREMENTS OF $CH_{4} \nu_{4}$ HALFWIDTHS USING TWO HIGH-RESOLUTION TECHNIQUES

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1985

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Ohio State University

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Air-broadened and N2-broadened halfwidths at room temperature for 25 lines in the ν4 band of 12CH4 have been determined from infrared absorption spectra recorded with a tunable diode laser (TDL) system in selected spectral regions between 1250 and 1360cm−1. Air-broadened halfwidths for 20 of these lines were also determined from additional spectra at 0.01cm−1 resolution recorded with the Fourier transform spectrometer (FTS) system in the McMath solar telescope complex on Kitt Peak. The air-broadened halfwidth values obtained from these two techniques are very consistent with agreement to better than 3% for most lines. Several additional lines of 13CH4 and 12CH3D were also measured in the same spectral region with the diode laser system. The measured N2-broadened and air-broadened halfwidths will be reported.

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Author Institution: Physics Department, College of William & Mary; Physics Department, NASA Langley Research Center; Physics Department, NASA Langley Research Center; Physics Department, College of William & Mary

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