DIODE LASER STUDIES OF COMPLEXES CONTAINING $CS_{2}$ AND $SO_{2}$
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Date
1992
Authors
Walsh, M. A.
Lewin, A.
Juang, Y. D.
Cruzan, J.
Hwang, C. H.
Dyke, T. R.
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Complexes of rare gases with $CS_{2}$ and of rare gases, nitrogen, and carbon monoxide with $SO_{2}$ in molecular beams have been studied by diode laser spectroscopy. The $SO_{2}$ monomer $v_{3}$ stretching region near $1362 cm^{-1}$ was exploited to give vibration-rotation spectra of Ne, Ar, $N_{2}$ and CO bound to $SO_{2}$. Similarly, the asymmetric stretch of $CS_{2}$ in complexes with Ne, Ar, Kr, and Xe was utilized to observe vibration-rotation spectra near $1535 cm^{-1}$. Rotational constants and vibrational band origin shifts were determined for these complexes. Some pure rotational spectroscopy has also been done, and is currently in progress, to supplement this data. The structures of the complexes and comparison of the results with model potentials will be discussed.""
Description
Author Institution: Lumonics Ltd., Cosford Lane Swift Valley; I.R.C. for Surface Science, University of Liverpool, L693BX; Department of Chemistry and Chemical Physics Institute, University of Oregon Eugene