MOLECULAR BEAM MAGNETIC RESONANCE STUDIES OF $N_{2}^{15*}$

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1961

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Ohio State University

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The rf spectra corresponding to the reorientations of the N15 nuclear moment and the molecular rotational moment have been studied in N215 by the molecular beam magnetic resonance method. A recently constructed beam apparatus with an electron bombardment detector was used for the experiments. In order to study these small moments, it was advantageous, to go to very narrow slits. The intensity of the beam was maintained at the normal level through the use of multiple bearns. Our experiments were carried out at magnetic fields of 7400 and 6700 gauss. From a preliminary analysis of the N15 nuclear resonance, the magnitude of the spin-rotational constant of N15 in N215 was determined to be 23±3 kcs. This can be shown to be consistent with available nitrogen chemical shift data. The magnitude of the rotational magnetic moment of N215 was found to be 0.2593±0.0005 nm.

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Work supported by the National Science Foundation and by the joint program of the Office of Naval Research and the U.S. Atomic Energy Commission. \dagNational Science Foundation Postdoctoral Fellow, 1960--61.


Author Institution: Lyman Laboratory of Physics, Harvard University

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