ANALYSIS OF THE $\nu_{2}$ BAND OF $D_{3}^{+}$

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1986

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Ohio State University

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Earlier ion-beam measurements1,2 of the ν2 band of the D3+ ion have now been supplemented with gas absorption measurements using diode laser sources and a cooled hollow-cathode discharge cell. At least 80 lines have been assigned and fitted using an effective Hamiltonian with a Pade representation of the centrifugal distortion effects3. These fits will be compared with others that include vibrationally off-diagonal interactions explicitly.

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1 J. -T. Shy, J. W. Parley, W. E. Lamb, Jr., and W. H. Wing, Phys. Rev. Lett. 45, 535 (1980). 2 J. -T. Shy, Ph. D. dissertation, University of Arizona (1982). 3 J. K. G. Watson, S. C. Foster, A. R. W. McKellar, P. Bernath, T. Amano, F. S. Pan, M. W. Crofton, R. S. Altman, and T. Oka, Can. J. Phys. 62, 1875 (1984). Address of Foster: Department of Chemsitry, The Ohio State University, Columbus, OH 43210. Address of McKellar and Watson: Herzberg Institute of Astrophysics, National Resarch Council of Canada, Ottawa, Ontario, Canada KIA OR6.


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