Fourier Transform Spectroscopy Analysis Of The 3d-Complex Visible Emission Spectra Of $H_{2}$ Experimental Results And Theoretical Interpretation

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1988

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Ohio State University

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An investigation of the triplet 3d-complex of H2, the g(3d)3Σg+,1(3d)3Σg and) (3d)3Δg and the nearby h(3s)3Σg+ state, has been performed 3s,3d<−−c(2p)3Πu visible emission spectra have been obtained with a low pressure discharge lamp and recorded by Fourier Transform Spectrometer. Transition wavenumbers and rotational energy levels are given for v=0−3 of the four states. The data are represented by an effective Hamiltonian which accounts for the rotational breakdown of the Born-Oppenheimer approximation (L-uncoupling) The eigenvectors obtained from this model provide considerable insight into the nature of the 3d-complex. It has been found necessary to include interactions with the h(3s)3Σg+ state to describe the complex for lower v values. Molecular constants are also given. Also for M Larzilliere: Laboratoire de Spectrometrie lonique et Moleculaire Associe au CNRS, Universite lyon-1, 69622 Villeurbanne Cedex, FRANCE

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Author Institution: Universite Laval, Departement de physique, CRAM-LPAM

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