THE HIGH RESOLUTION MAGNETIC CIRCULAR DICHROISM SPECTRUM OF Cs $ZrCl_{6}$: $Ir^{4+}$

Thumbnail Image

Files

1970-K-02.jpg (86.32 KB)

Date

1970

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

High resolution absorption and magnetic circular dichroism (MCD) spectra of crystals of Cs2ZrCI6 doped with IrCI62− have been recorded over the spectral region 15 500 to 39000cm−1 at liquid helium temperature. The absorption spectrum shows a great wealth of fine structure in general agreement with the results of Douglas1 but with some additional detail due to higher resolution running conditions. The MCD spectrum is remarkably well resolved, in general showing a distinct feature corresponding to every absorption line. A preliminary analysis of these spectra will be given, and it will be shown that the Douglas interpretation is incorrect in a number of important respects.

Description

This work was supported by a grant from the National Science Foundation. 1I. N. Douglas, J. Chem. Phys. 51, 3066 (1969).""


Author Institution: Chemistry Department, University of Virginia

Keywords

Citation

URI

http://hdl.handle.net/1811/8458

Collections

Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979