INFRARED AND MICROWAVE SPECTRA OF ClCN

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1964

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Ohio State University

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High resolution infrared spectra of $Cl^{35}CN$ and $Cl_{37}CN$ have been obtained in the region 2000 to $3000 cm^{-1}$. The bands $\nu_{3}, \nu_{3}+\nu_{2}^{1},\nu_{3}+2\nu_{2}^{0}$ and $\nu_{2}+\nu_{1}$ have been analyzed for both isotopic species and their vibrational-rotational constants will be reported. In addition, the pure rotational spectra of these molecules in the states $2\nu^{0}_{2}, 2\nu^{2}_{2}$ and $\nu_{1}$ have been obtained. The Fermi resonance between $\nu_{1}$ and $2\nu^{0}_{2}$ and $\nu_{3}+2\nu^{0}_{2}$ and $\nu_{3}+\nu_{1}$ will be discussed.

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Author Institution: National Bureau of Standards

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