THE POLARIZED ULTRAVIOLET REFLECTION SPECTRA AND THE ELECTRONIC STRUCTURE OF Pd(II) AND Pt(II) SQUARE-PLANAR TETRAAMMINE COMPLEXES.
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Date
1969
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Publisher
Ohio State University
Abstract
Recent studies in this laboratory have suggested that the relatively low-lying allowed transitions in planar $d^{8}$ complexes may in some cases involve a $d \rightarrow p$ type ``metallic'' transition. In order to investigate this possibility further, the polarized single-crystal reflection spectra of the square-planar tetraammine complexes of palladium(II) and platinum(II) have been determined. These spectra will be reported and discussed in light of previous results obtained here and elsewhere, and in terms of existing theory for planar complexes.
Description
Partial support has been provided by the National Institutes of Health for this research. Stephen I. Foster was a National Defense Education Act Fellow. Permanent address of Nozomu Takeuchi: Faculty of Engineering, Tokushima University, Tokushima, Japan.
Author Institution: Basil Chemistry Department, New Mexico State University; Faculty of Engineering, Tokushima University
Author Institution: Basil Chemistry Department, New Mexico State University; Faculty of Engineering, Tokushima University