HIGH RESOLUTION LASER-INDUCED FLUORESCENCE SPECTROSCOPY OF Zn $CH^{35}$ $CdCH_{3}$ AND $He-CdCH_{3}$

Research Projects

Organizational Units

Journal Issue

Abstract

The jet cooled, laser-induced fluorescence spectra of the A~2EX~2A1 transition in ZnCH3 and CdCH3 have been previously reported by this laboratory.1 These organometallic radicals were formed by photolysis of the metal dimethyl compound, M(CH3), where M=Zn, Cd. The focus of the initial report involved the vibronic and spin-orbit structures in the electronic spectra of ZnCH3 and CdCH3. We new report an analysis of the rotationally resolved spectra of the origin band for each of these radicals. A spectroscopic study of the inert-gas molecular Van der Waals complex, HeCdCH3, was included in that first report.1 The rotationally resolved spectrum of this complex has been recorded and will be discussed.

Description

1E.S. Robles, A.M. Ellis and T.A. Miller, Chem. Phys. Lett. 178, 185 (1991).


Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University; Department of Chemistry, University of Leicester; Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University; Laser Spectroscopy Facility, Department of Chemistry, Naval Surface Warfare Center; Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University

Keywords

Citation