A SIMPLE FACTORIZATION SCHEME TO PREDICT IVR RATES IN MEDIUM-SIZED ORGANIC MOLECULES
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Abstract
Other factors being equal, it has long been assumed that the IVR rate will decrease as the symmetry of the molecule increases. Recently, Callegari, et al. observed no trend: increasing rates of IVR in a progression from s-triazine to pyrrole to benzene in the first CH stretching overtone bands. The simple factorization method previously
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Author Institution: Department of Chemistry and Beckman Institute for Advanced Science and Technology, University of Illinois