MOVEMENT OF MATRIX ISOLATED AMMONIA, VIBRATIONAL RELAXATION
Loading...
Date
1974
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The structure observed between 900 and $1020 cm^{-1}$ in the infrared spectra of monomeric $NH_{3}$ trapped in Ne, Ar, Kr and Xe matrices, can be explained with the assumption of molecular rotation and inversion of ammonia in the matrix. The nuclear spin species conversion, easily observed, seems to be a first order phenomenon; it takes place in about 3 hours at $8^{\circ} K$. To explain the complex structure of the spectra in neon matrices, we are led to suppose the coexistence of the fee and hep phases in the neon polycrystalline sample. The rotation is almost free and the barrier parameter K, as defined by Deonvshire, increases from neon to xenon; the steric factor is not the most important in the hindering to rotation. [FIGURE] In solid nitrogen, the ammonia molecule undergoes a movement of libration in the matrix cage. Time resolved infrared double resonance spectroscopy, which has proven to be a useful technique for the study of vibrational relaxation in laser excited molecules, gave the following results: in nitrogen matrices the $\nu_{2}$ = 1 life-time is about 2$\mu s$ at 8 $^{\circ} K$, and in argon and methane it is shorter than 500 ns.
Description
Author Institution: Laboratoire de Photophysique, Moleculaire Bat. 213 Universite de Paris