SPECTROSCOPIC INVESTIGATION OF THE STRUCTURES OF COMPLEXES OF PLATINUM (II) WITH UNSATURATED LIGANDS CONTAINING $\alpha$-HYDROXYL GROUPS

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1964

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Ohio State University

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The infrared spectra of platinum (II) complexes containing the dihydroxyacetylene, Me2C(OH)−C≡CC(OH)Me2, and allyl alcohol, CH2=CHCH2OH, have been examined, particularly in the O-H stretching frequency region (3000−3700cm.−1) in order to determine the role of the hydroxyl groups in complex formation. The effect on this frequency of the addition of basic solvents (ether, R3N, py, α,α-lutidine) to solutions of the free ligand and the complexes was also examined. A discussion of the possible factors influencing the stability and the structure of these complexes is presented.

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\dag Present address: Howard University, Department of Chemistry, Washington 1, D. C.


Author Institution: University of Toronto

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http://hdl.handle.net/1811/14614

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969