MILLIMETER WAVE SPECTROSCOPY OF THE BENDING VIBRATION OF THE CO-$orthoN_{2}$ COMPLEX
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Date
2001
Authors
Surin, L. A.
Müller, Holger S. P.
Winnewisser, G.
Pak, I.
Dumesh, B. S.
Alieva, E. V.
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The bending vibration of the $CO-N_{2}$ complex has been investigated in the millimeter wave range from 130 to 150 GHz using an intracavity OROTRON jet spectrometer. Initial line positions were based on the IR observation of a bending state for CO-$orthoN_{2}.^{a}$ Six transitions P(2), P(1), R(0), R(1), R(2) and R(3) associated with the ground and bending state K = 0 levels of the $orthoN_{2}$ spin modification were measured and analyzed. Nuclear quadrupole structure due to the presence of two equivalent $^{14}N$ nuclei was partly resolved and analyzed to give information about the angular anisotropy of the interaction potential. The quadrupole splitting also facilitated the assignments. The determined frequency of the bending vibration is 139892.459(35) MHz. The nuclear quadrupole coupling constant obtained for the first time for the bending state of CO-$orthoN_{2}$ is $\chi_{aa} = - 0.768(43) MHz$. The drastic difference of this constant from the same one in the ground state suggests that the orientation and motion of the $N_{2}$ subunit are very different in these two states.
Description
$^{a}$C. Xia, A. R. W. McKellar, and Y. Xu, J. Chem. Phys. 113, 525 (2000).
Author Institution: Steacie Institute for Molecular Sciences, Universit\""at zu K\""oln, Z\""ulpicherstr; I. Physikalisches Institut, Universit\""at zu K\""oln, Z\""ulpicherstr; I. Physikalisches Institut, Insitute of Spectroscopy
Author Institution: Steacie Institute for Molecular Sciences, Universit\""at zu K\""oln, Z\""ulpicherstr; I. Physikalisches Institut, Universit\""at zu K\""oln, Z\""ulpicherstr; I. Physikalisches Institut, Insitute of Spectroscopy