EVIDENCE FOR NOBLE GAS-METAL CHEMICAL BONDING: FT-MICROWAVE SPECTRA, GEOMETRIES AND HYPERFINE CONSTANTS OF THE COMPLEXES Ar-CuX (X=F, Cl, Br).
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Abstract
The rotational spectra of the complexes Ar-CuF, Ar-CuCl and Ar-CuBr have been measured between 5-22 GHz using a cavity pulsed jet Fourier transform microwave spectrometer. They were prepared by ablating Cu metal with a Nd: YAG laser (532 nm) and allowing the vapour to react with a suitable precursor contained as
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Author Institution: Department of Chemistry, University of British Columbia