THE PFI-ZEKE PHOTOELECTRON SPECTROSCOPY OF $C_{2}H_{2}$ AND $C_{2}D_{2}$ NEAR ITS IONIZATION THRESHOLD

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1997

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Ohio State University

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The 1+1 two-colour pulsed-field induced zero-kinetic-energy (PFI-ZEKE) photoelectron spectra of C2H2 via a single rovibronic level of the A¯1Au state of acetylene were previously reported by Pratt etalg. In this work, with similar approach the effects of the pulsed-field strengths and the rovibronic symmetries of the intermediate states of C2H2 and C2D2 on the PFI-ZEKE photoelectron spectra near the ionization threshold were investigated and will be reported. Although the number of observed transitions was limited, the spectroscopic constants of the zero-point energy levels of C2H2+ obtained from the best fit are in good agreement with those reported by Jagod etalh: B=1.098±0.002cm−1,A80(spin-orbit constant)=−30.84±0.05cm−1, and IP0=91967.06±0.03cm−1. Those of C2D2+ are B=0.82±0.03cm−1,A80=−31.1±0.3cm−1, and IP0=92004.7±0.3cm−1.IP0 is defined as the energy difference between the zero point levels of the ground states of the neutral and its cation. We propose to use IP0 to denote the ionization potential of the molecule, of which the cation belongs to the Hund’s case(b) coupling.

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gS.T. Pratt, P. M. Dehmer, and J. L. Dehmer, J. Chem. Phys. 99, 6233 (1933). hM. F. Jagod, M. R""{o}sslein, C. M. Gabrys, B.D. Rehfuss, F. Scappini, M. W. Crofton, and T. Oka, J. Chem. Phys. 97, 7111 (1992).


Author Institution: Institute of Atomic and Molecular Sciences Department of Chemistry, Academia Sinica National Taiwan University

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