CARBON-13 SPIN ROTATION CONSTANT OF $^{13}CH_{4}$
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Date
1972
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
$^{13}CH_{4}$ has been studied by the molecular-beam magnetic resonance method in the high-field limit. The spectrum observed corresponds to the reorientation of the carbon-13 nuclear spin with respect to the external magnetic field H. The transition frequencies have been calculated as functions of the molecular coupling constants by perturbation theory to order 1/$H^{2}$. The terms from the proton-carbon dipole-dipole interaction have been determined by the method of Yi, Ozier and $Anderson.^{1}$ It has been found that the magnitude of the carbon-13 spin-rotation constant is $(15.94 \pm 0.35)$ kHz. This work was supported in part by the National Science Foundation (U.S.A.) and the National Research Council (Canada). I. Ozier has been an Alfred P. Sloan Fellow.
Description
$^{1}$ P.N. Yi, I. Ozier and C.H. Anderson, Phys, Rev. 165, 92 (1968).""
Author Institution: Department of Physics, University of British Columbia; Lyman Laboratory of Physics, Harvard University
Author Institution: Department of Physics, University of British Columbia; Lyman Laboratory of Physics, Harvard University