EXPERIMENTAL DETERMINATION TO LARGE INTERNUCLEAR SEPARATION OF THE '$\Sigma^{+}$ STATE ELECTRIC DIPOLE MOMENT FUNCTION OF CO
Loading...
Date
1983
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
We have experimentally determined the EDMF of CO’s ground electronic state to about the classical turning points of the V=40th level. The $Pade’$ approximant representation of the EDMF is determined via a non-linear least-squares fit which combines numerically obtained vibrational wavefunctions and experimentally determined vibrational band intensities for which $\Delta v=1,2,3$ and 40 for both emission spectra by considering pairs of vibrational transitions from common upper vibrational states and assuming a well defined rotational temperature. These results should be useful in the interpretation of solar infrared spectra.
Description
Author Institution: NASA Ames Research Center, Astrophysical Experiments Branch; Laboratoire d' Infrarouge, Universite de Paris-Sud. Campus; Institut for Angewandte Physik der, Universitat Bonn Wegel str. 8, 0-5300