CW-CRDS OF THE OZONE MOLECULE IN THE 5905-5960 $cm^{-1}$ REGION: FIRST OBSERVATION AND ANALYSES OF THE $\nu_1$+$3\nu_2$+$3\nu_3$ AND $4\nu_1$+$\nu_2$+$\nu_3$ BANDS
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Date
2007
Journal Title
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Publisher
Ohio State University
Abstract
This work continues the systematic study of the rovibrational spectra of ozone in the infrared}, newly using the high sensitivity CW-cavity ring down spectroscopy ($\alpha_{min}$ $\approx$ $3\times 10^{-10}$ $cm^{-1}$)}, \textbf{$780-781$}, 225-233, (2006).} }, \textbf{$240$}, 1-13, (2006).} }, under press, (2007).} }, submitted, (2007).}. Here, we observe two new A type bands, where the main contributers are $\nu_1$+$3\nu_2$+$3\nu_3$ and $4\nu_1$+$\nu_2$+$\nu_3$ centered at 5919.154 and 5947.071 $cm^{-1}$ respectively. We report for each of them the Hamiltonian parameters, the transition moment parameters, the range of observed quantum numbers, the statistics for line position and intensities, the list of "observed energy levels", with the comparison with their calculations and we show various examples of agreements between observed and calculated spectra. In addition, a comparison between observed and predicted band center }$ International Conference on High Resolution Molecular Spectroscopy}, Praha, (2006), to be published.} will also be discussed.
Description
Author Institution: Groupe de Spectrometrie Moleculaire et Atmospherique,; U.M.R. CNRS 6089, Universite de REIMS, Moulin de la Housse, B.P. 1039,; 51687 REIMS cedex 2, FRANCE; Laboratoire de Spectrometrie Physique, U.M.R. CNRS 5588, Universite Joseph Fourier; B.P. 87, 38402 Saint Martin d'Heres cedex, FRANCE