Knowledge Bank

High resolution optothermal spectra have been obtained for the Ar-HCl (v=1) and Ar-DF (v=1) complexes. In both complexes, the vibrational predissociation lifetime is found to be greater than the time of flight of the complexes from the point of excitation by an F-center laser to the bolometer detector. This places a lower limit on the lifetime of 0.6 ms, in analogy to earlier reported Ar-HF (v=1) measurements. In addition to this, Stark spectra have been obtained for both complexes to determine the vibrational excited state dipole moments. These will be compared with the theoretical values.