OPTICALLY PUMPED FAR-INFRARED LASERS FROM METHANOL ISOTOPOMERS: $^{12}CD_{3}OH$, $^{12}CH_{3}OD$, AND $^{12}CH_{2}DOH$; NEW LASER LINES AND FREQUENCY MEASUREMENTS

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1996

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Ohio State University

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Methanol and ten of its isotopomers have generated over 2000 far-infrared laser lines when pumped by $CO_{2}$ lasers. We report here 28 new laser lines from the isotopomers $^{12}CD_{3}OH$, $^{12}CH_{3}OD$, $^{12}CH_{2}DOH$ along with their frequencies, relative intensities, relative polarizations and pump offsets. An efficient $CO_{2}$ laser with extended line coverage provided pumping from high J-fundamental, sequence and hot-band $CO_{2}$ transitions. Many new short-wavelength (below 100 $\mu$m) FIR laser transitions were observed.

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Author Institution: Instituto de Fisica Gleb Wataghin, Departamento de Eletronica Quantica, Universidade Estadual de Campinas (UNICAMP); Time and Frequency Division, National Institute of Standards and Technology

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