SPECTROSCOPY AND DYNAMICS OF THE $\widetilde{A}^{2}A^{\prime\prime}$ STATE OF VINYL RADICAL

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2002

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Ohio State University

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Abstract

The vibrational structure of the $\widetilde{A}^{2}A^{\prime\prime}$ state of vinyl radical has been investigated by photofragment detection. The subsequent dynamics from the $\widetilde{A}^{2}A^{\prime\prime}$ state were elucidated with ion imaging, revealing the partitioning of energy between the products, H and $C_{2}H_{2}$. Results will be discussed in comparison to recent theoretical predictions.

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Author Institution: Department of Chemistry, The Ohio State University

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