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Recently, the dissociation mechanism of HCN by vibrationally mediated photodissociation has been examined. Exciting the C-H strerch with four quanta and photodissociating the molecule with 220 nm light generates CN in the first excited electronic $A~2\Pi$ state rather than the ground $X~2\Sigma +$ state. The CN fragment is detected by probing the $B~2\Sigma +\leftarrow A~2\Pi (1-0)$ band and monitoring the laser induced fluorescence (LIF) via the $B~2\Sigma +\to X~2\Sigma \Pi$ transition. Progress on the analysis of the LIF spectrum and the nascent product distribution will be presented.