INTRACAVITY LASER ABSORPTION SPECTROSCOPY - A COMPARISON WITH CLASSICAL ABSORPTION - LINE SHAPES AND QUANTITATIVE MEASUREMENTS

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1983

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Ohio State University

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Using a CW dye laser for intracavity laser absorption spectroscopy (ICLAS) with a controlled time generation and a time-resolved spectrum, we show that intracavity absorption follows the Lambert Beer Law. By comparing the absorption of the very weak γ band of O2b1Σg+(v=2)←X3Σg(v=0) in ICLAS and in multi-pass cell technique1 we confirm that the intracavity technique gives reproducible results under different experimental conditions and is a highly sensitive quantitative method for measuring absolute absorption coefficients and collision broadening coefficients. This method does not necessitate any previous scaling in contrast with other sensitive methods like photo-acoustic or optogalvonic techniques. 1J. J. Miller, L. P. Giver, R. W. Boese, J.Q.S.R.T. 16 (1976) 595.

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Author Institution: Laboratoire de Spectrometrie Physique Universite Scientifique et M'edicale de Grenoble - BP68 38402, Saint Martin d'H'eres

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