METAL-MOLECULE INTERACTIONS IN $In^{+}-NH_{2}(CH_{3})$, $In^{+}-NH(CH_{3})_{2}$, $In^{+}-N(CH_{3})_{3}$ and THEIR NEUTRAL RADICALS

dc.creator	Rothschopf, Gretchen K.	en_US
dc.creator	Li, Shenggang	en_US
dc.creator	Yang, Dong-Sheng	en_US
dc.date.accessioned	2006-06-15T20:10:58Z
dc.date.available	2006-06-15T20:10:58Z
dc.date.issued	2001	en_US
dc.description	Author Institution: Department of Astronomy \& Astrophysics, and the Enrico Fermi Institute, University of Kentucky; Department of Chemistry, University of Kentucky	en_US
dc.description.abstract	The indium-amine radicals were produced by reactions of laser-vaporized metal atoms with methylamines seeded in helium gas and identified with time-of-flight mass spectrometry. Metal-ligand interactions of the positive ion and neutral species were probed using ZEKE spectroscopy. From the ZEKE spectra, ionization energies and metal-ligand stretching frequencies were determined for the three complexes, and bending frequencies were obtained for the monomethylamine and dimethylamine species. In comparison with $InNH_{3},^{a}$ these methylated complexes have lower ionization energies and stronger metal-ligand binding. $^{a}$G. K. Rothschopf, J. S. Perkins, S. Li and D. -S. Yang, J. Phys. Chem. A 104, 8178 (2000).	en_US
dc.format.extent	163928 bytes
dc.format.mimetype	image/jpeg
dc.identifier	2001-RC-03	en_US
dc.identifier.uri	http://hdl.handle.net/1811/20108
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	METAL-MOLECULE INTERACTIONS IN $In^{+}-NH_{2}(CH_{3})$, $In^{+}-NH(CH_{3})_{2}$, $In^{+}-N(CH_{3})_{3}$ and THEIR NEUTRAL RADICALS	en_US
dc.type	article	en_US

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