IDENTIFICATION OF THE nf COMPLEXED IN $N_{2}$ BY UV ABSORPTION

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1983

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Ohio State University

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Absorption features at λ=824,815, and 810\AA are identified as the 5f, 6f, and 7f complexes in molecular nitrogen. Our study of the 7f complex at 810\AA shows that the main lines are separated by 4B(B2cm−1) rather than 2B and can be labeled as members of the O and the S branches. Theoretical analysis in terms of the frame transformation theory1 yields line positions and strengths similar to the L complex theory.2 Generally excellent agreement is found between theory and experiment. This work was supported by the Air Force under AFGL Contract #F19628-81-K-0007. 1E.S. Chang and U. Fano, Phys. Rev. A 6. 173 (1972) 2Ch. Jungen and E. Miescher, Can. J. Phys. 47, 1769 (1969).

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Author Institution: Department of Physics and Astronomy, University of Massachusetts Amherst; Center for Astrophysics Harvard, University Cambridge

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