THE MICROWAVE SPECTRUM OF $N^{14}O^{16}O^{17}$

Foster, Peter D.; Hodgeson, Jimmie A.; Curl, R. F., Jr.

THE MICROWAVE SPECTRUM OF $N^{14}O^{16}O^{17}$

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Date

1966

Authors

Foster, Peter D.

Hodgeson, Jimmie A.

Curl, R. F., Jr.

Publisher

Ohio State University

Abstract

Some 150 hyperfine transitions belonging to the $S 08 →7 17$ and $919 →10 0,10$ rotational transitions of $N 14 O 16 O 17$ have been observed in the microwave region. The new coupling constants which have been determined are the odd-electron expectation values on oxygen. They are $| ψ (0)| 2 =0.71×10 24 c m −3,< 3 r^a 2 −1 r 3 >=−4.71×10 24 c m −3$ and $< (r^b − i r^c) 2 r 2 >=5.04×10 24 c m −3 .$ The results of the work are combined with previous work on other isotopic modifications of $N O 2$ to give a LCAO-MO picture of the odd electron orbital. This work was supported by Grant C-071 of The Robert A. Welch Foundation and in part by Grant GP-4166 from the National Science Foundation.

Description

Author Institution: Department of Chemistry, Rice University

URI

http://hdl.handle.net/1811/15004

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969

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