USE OF FORBIDDEN TRANSITION FOR A BETTER DETERMINATION OF MOLECULAR PARAMETERS IN THIONYL FLUORIDE MOLECULE

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1974

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Ohio State University

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The thionyl fluoride molecule belongs to the point group $C_{s}$, and the electric dipole moment components on the principal axes are $\mu_{a}$ and $\mu_{c}$. The determination of molecular parameters has been obtained from a and c type $transitions.^{1,2}$ By the application of an electric field, forbidden b type transitions may be observed. A better definition of molecular parameters has been obtained by use of these results.

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$^{1}$R. C. Ferguson, J. Amer. Chem. Soc. 76, 850 (1954). $^{2}$Lucas and Smith, J. Mol. Spectrosc. 43, 327 (1972).
Author Institution: Laboratoire de Spectroscopie Hertzienne, Universite des Sciences et Techniques

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http://hdl.handle.net/1811/16534

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979