THE VIBRATIONAL SPECTRA OF MOLECULAR IONS FORMED FROM HBr AND HI AND TRAPPED IN SOLID NEON

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1995

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Ohio State University

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When a Ne:HBr or a Ne:HI sample is codeposited at 5 K with a beam of neon atoms that has been excited by a microwave discharge, the solid deposit shows prominent infrared infrared absorptions of the HX+,(HX)2+, and XHX− ion products. The vibrational spectra of these species and their behavior on subsequent exposure of the deposit to various ranges of visible and ultraviolet radiation are compared with the corresponding properties previously observed for Ne:HCl samples.

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Author Institution: National Institute of Standards and Technology, Gaithersburg, MD 20899.

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http://hdl.handle.net/1811/29759

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999