AN IMPROVED SYSTEMATIC PROCEDURE FOR PERTURBATION CALCULATIONS, WITH APPLICATION TO ROTATING-VIBRATING DIATOMIC MOLECULES THROUGH SIXTH ORDER.

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1969

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Ohio State University

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Abstract

An improved systematic organization of non-degenerate perturbation theory and the contact transformation of the hamiltonian will be presented which facilitates the determination of the higher-order portions of the rotation-vibration energy for a molecule. The discussion will include application of the method of calculation of the energies of a rotating vibrating diatomic molecule through sixth order of approximation and comparison with Dunham's result obtained by the WKB method.

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Author Institution: Department of Physics, The Ohio State University

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http://hdl.handle.net/1811/15675

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969