DFT TEST STUDY ON VAN DER WAALS DIMERS

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2000

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Ohio State University

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Abstract

Studies in the framework of the supermolecule approach, using density functional theory with basis sets optimized for generalized gradient approximation exchange-correlation calculations, and constructed to give accurate values for nonbonding interaction, will be discussed. Bonding properties of the diatomic van der Waals $CO - He$ and $N_{2} - He$ molecules will be presented and compared with recent experimental and theoretical results.

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Author Institution: Department of Chemistry, Simon Bolivar University; Department of Chemistry and Biochemistry, Baylor University

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