INFRARED SPECTRA OF BENZENE-DIACETYLENE CLUSTERS: $C_{6}H_{6} \cdot C_{4}H_{2}$ and $C_{6}H_{6} \cdot (C_{4}H_{2})_{2}$

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2002

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Ohio State University

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Resonant two photon ionization spectra of the benzene:diacetylene 1:1 cluster have been taken across the $6^{1}{_{0}}$ transition region of the cluster with time-of-flight mass spectrometry detection. IR/UV holeburning has shown that one of the peaks in the spectrum is the benzene:diacetylene 1:2 cluster. The resonant ion dip infrared spectra of both the 1:1 cluster and the 1:2 cluster have been recorded. Possible structures of these clusters will be discussed.

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Author Institution: Department of Chemistry, Purdue University

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