ABSOLUTE RADIATIVE TRANSITION PROBABILITIES OF THE $A^{1}\Sigma_{u}^{+} \leftrightarrow X^{1}\Sigma_{g}^{+}$ BANDS OF $^{7}Li_{2}$
Loading...
Date
1978
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Using accurate hybrid potential curves and an ab initio transition moment function, we have calculated absolute radiative transition probabilities for most $(v^{\prime}\leq 70, v^{\prime\prime} \leq 40)$ vibrational levels in the $A^{1} \Sigma^{+}_{u}\longleftrightarrow X^{1} \Sigma^{+}_{g}$ bands of $^{7}Li_{2}$. We are presently modifying our computer programs to calculate the transition probabilities for the remaining vibrational levels (up to $v^{\prime} \approx 115!)$. We shall relate these calculations to our current experimental plans for observation of the highest vibrational levels in the $X^{1} \Sigma^{+}_{g}$ and $A^{1} \Sigma^{+}_{u}$ states.
Description
This research was supported by the National Science Foundation.
Author Institution: Department of Chemistry, Wartburg College; Departments of Chemistry and Physics, University of Iowa
Author Institution: Department of Chemistry, Wartburg College; Departments of Chemistry and Physics, University of Iowa